H2SO4(aq) + Ba(OH)2(aq) BaSO4(s) + 2 H2O(l), Heildarhagfri - 10,11,12,13 - Fyrirlestrar, Pre-Lecture Chapter 7 General Chemistry 1, Oxidizing and Reducing Agents Assignment and, Bruce Edward Bursten, Catherine J. Murphy, H. Eugene Lemay, Matthew E. Stoltzfus, Patrick Woodward, Theodore E. Brown, Chapter 4 commercial ref. How many molecules are present in 4.25 mol of CCl4? Bond dissociation energies: Since all ammonium salts are soluble in water, the only precipitate has to be zinc sulfide C7H16 + O2 7 CO2 + 8 H2O. A) if the value of G for a reaction is negative, the reaction is said to be spontaneous. C3H8 + 5 O2 3 CO2 + 4H2O Balance the equation (NH4)2SO4 + Ba(C2H3O2)2 = BaSO4 + NH4C2H3O2 using the algebraic method. C) Reactants are being consumed at the same rate they are being produced. Ammonium sulfate reacts with barium nitrate to form ammonium nitrate and barium sulfate. Now, the net ionic equation is, K2CO3(aq)+Sr(NO3)2(aq)2KNO3(aq)+SrCO3(s), 2K+(aq)+CO32(aq)+Sr2+(aq)+2NO3(aq)2K+(aq)+2NO3(aq)+SrCO3(s). Which of the following states of matter should have the lowest entropy value? oxidation number is ________. Calculate the number of moles of aspirin, C9H8O4, in 4.0 gram sample. ________ C5H12 + ________ O2 ________ CO2 + ________ H2O. Which of the following is always a spectator ion in aqueous chemical reactions? Asked for: reaction and net ionic equation Based on the reaction shown, which statement is true? The sulfate anion test also proved positive, as a white precipitant was formed when the unknown substance was mixed with barium chloride and hydrogen chloride; the mixture between barium and sulfate is also insoluble according to the solubility rules. (NH4)2SO4 + Ba (NO3)2 ==> 2NH4NO3 + BaSO4 It is a double replacement reaction. To identify a precipitation reaction and predict solubilities. Ethyl Acetate C4H9OH Butyl Alcohol C5H10 Cyclopentane C5H10O5 Ribose C5H12 Pentane Lets consider the reaction of silver nitrate with potassium dichromate above. When the reaction shown is correctly balanced, the coefficients are: E) the reaction rate is determined by the value of G. E) the reaction rate is determined by the value of DELTA G. 2 Al2O3(s) --> 4 Al(s) + 3 O2(g) Aqueous solutions of rubidium hydroxide and cobalt(II) chloride are mixed. reacted with nitrogen, 1575 g of ammonia were produced. B) gaining hydrogen. B) a reducing agent causes another substance to be reduced. Because both components of each compound change partners, such reactions are sometimes called double-displacement reactions. (NH4)2SO4 (aq) + Ba(C2H202)2 (aq) - BaSO4(s) + NHC2H2O2 (aq). Aqueous solutions of rubidium hydroxide and cobalt(II) chloride are mixed. The idea here is that you're mixing two solutions that contain soluble ionic compounds and you're interested in finding out if an insoluble ionic compound can be formed by the reaction. Study with Quizlet and memorize flashcards containing terms like Lead(II) acetate and sodium bromide, Lithium phosphate and calcium sulfide, Potassium chloride and barium hydroxide and more. from 8.55 mole of nitrogen. The equation is now balanced because there is an equal amount of substances on the left and the right hand side of the equation. On the left hand side there are 2 O atoms and the right hand side only has one. The concept of free energy allows prediction of spontaneity of a process by considering the changes You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Write the balanced equation, include states, for the reaction between solutions of: a) potassium hydroxide and lead(II) nitrate (Click for the solution to a) b) lead(II) nitrate and iron(II) sulfate c) ammonium sulfate and barium chloride d) copper(II) sulfate and sodium carbonate e) silver nitrate and sodium chloride Suppose 23.8 g of barium acetate is dissolved in 250. mL of a 0.60 M aqueous solution of ammonium sulfate. E) One mole of bromine, Br2, contains the same number of molecules as one mole of propane, Which reaction is an example of both a precipitation and a neutralization? The oxidation number of chlorine in the compound FeCl3 is, All of the reactions shown are oxidation-reduction reactions except. Both these points apply to the reactants. formed from 89.5 kg of hydrogen. The overall balanced chemical equation for the reaction shows each reactant and product as undissociated, electrically neutral compounds: \[\ce{2AgNO_3(aq)} + \ce{K_2Cr_2O_7(aq)} \rightarrow \ce{Ag_2Cr_2O_7(s) }+ \ce{2KNO_3(aq)} \label{4.2.1a} \]. Thus Pb(C2H3O2)2 will dissolve, and PbI2 will precipitate. The balanced equation will appear above. B) allows us to identify an exothermic reaction. The last column of the resulting matrix will contain solutions for each of the coefficients. Thus BaSO4 will precipitate according to the net ionic equation, \[Ba^{2+}(aq) + SO_4^{2-}(aq) \rightarrow BaSO_4(s) \nonumber \]. R Q 5/30/17 - 2342, UNIT 3 Personal and Professional Survival Gui. All of the statements regarding the symbol DELTA G are true except it 29) Which reaction is an example of a precipitation reaction? The equation will now look like this: This equation is a balanced equation because there is an equal number of atoms of each element on the left and right hand sides of the equation. Which of the following will affect all reaction rates? The formula weight of ammonium carbonate, (NH4)2CO3 is ________ amu. D) if the value of G for a reaction is 55.2 kcal, the value of G for the reverse reaction will be If a precipitate forms, write the net ionic equation for the reaction. + 6. 2 moles C4H10, What does the balanced equation given below mean? particles or units of that substance. acetate is. (d) -hc, where h is Planck's constant. The easiest way to make that kind of prediction is to attempt to place the reaction into one of several familiar classifications, refinements of the five general kinds of reactions (acidbase, exchange, condensation, cleavage, and oxidationreduction reactions). In order to determine if a reaction is at equilibrium which of the following must be true? Hydrogen sulfate + Sodium hydrogen carbonate 5. If 4.65 moles of propane, C3H8, are The solubility and insoluble annotations are specific to the reaction in Equation \ref{4.2.1} and not characteristic of all exchange reactions (e.g., both products can be soluble or insoluble). that is the correct . Calculate the molar solubility of BaSO 4 and the mass of barium present in 1.00 L of water saturated with BaSO 4. DELTA G = +138 kcal . H8N2O4S + Ba(C2H3O2)2 = BaO4S + NH4C2H3O2 might be a redox reaction. Which is the correct equation for the reaction of magnesium with hydrochloric acid to produce What is the percent yield if the A) forming an anion from a neutral atom. 8/31/2015. C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(l), The combustion of propane gas (C3H8) is used to fuel barbeque grills. D) occur at low temperatures but not at higher temperatures. Phosphoric Acid + Magnesium H 7. Subscripts may be changed to make an equation simpler to balance. Information about the equation, such as the type of reaction may also be calculated. 2 Fe + 3F2 --> 2 FeF3, The Haber process is used to make ammonia, which is an important source of nitrogen that can be EXAMPLE 4. Sodium acetate and ammonium sulfate are both soluble ionic compounds, which implies that they exist as ions in aqueous solution. The element chlorine is very reactive as a(an) ________ agent because it readily ________ electrons For the reaction given below, what quantity of heat will be produced if 90.0 g of C3H8 are The number of grams in 0.350 mol of Na is. How many grams of C will be consumed when 5.00 grams of Na2SO4 react according to the balanced Thus, each side of the equation must represent the same quantity of any particular element. B) One mole of solid tetraphosphorus decaoxide reacts with six moles of liquid water to produce Predict the products and write the balanced net ionic equation for the reaction that occurs between barium acetate and ammonium sulfate. C) redox reaction Q: Write (a) molecular, (b) total ionic, and (c) net ionic equations for each of the following. 5. D) combustion could. high temperature, this reaction is probably ________. A solution is made by dissolving 18.4 g of HCl in enough water to make 662 mL of solution. Free and expert-verified textbook solutions. What mass of CO2 Because strontium sulfate is much less soluble in water than strontium chloride, sodium chloride, or sodium sulfate, this reaction is: Na2SO4 (aq) + SrCl2 (aq) => 2 NaCl (aq) + SrSO4 (s). When aqueous solutions of silver nitrate and potassium dichromate are mixed, silver dichromate forms as a red solid. An aqueous solution of strontium hydroxide is added to an aqueous solution of iron(II) chloride. 2 Cr(s) + 3 Cl2(g) 2 CrCl3(s), The balanced equation for the reaction occurring when iron(III) oxide, a solid, is reduced with pure -55.2 kcal. When the reaction shown is correctly balanced, the coefficients are: (a) Solid potassium chlorate, KClO 3 decomposes to form solid potassium chloride and diatomic oxygen gas (b) Solid aluminium metal reacts with solid diatomic iodine to form solid Al 2 I 6 (c) When solid sodium chloride is added to aqueous sulfuric acid, hydrogen chloride gas and aqueous sodium sulfate are produced. B) allows us to identify an exothermic reaction. We can say that this reaction is ________ and that the sign of H is ________. sulfate, CaSO4. Removing products as they are formed 8/31/2015. Oxidizing agent - Wikipedia. C) metal ions are produced when pure metals are oxidized. RESULTS PRECIPITATION REACTIONS CHEM 101 LAB #8 N1 Ammonium Chloride and Copperfil) Sulfate Formation of Precipitate Color of Precipitate Formula of Precipitate Observations OBJECTIVES Observe Physical and Chemical changes Give evidence for the accurrence of a chemical reaction Write balanced chemical equations Write balanced net ionic equations Chemical Equation Net lonic Equation . Since there is an equal number of each element in the reactants and products of H8N2O4S + Ba(C2H3O2)2 = BaO4S + 2NH4C2H3O2, the equation is balanced. Nothing precipitates . monoxide? calcium carbonate are contained in a tablet weighing 550. mg? We will discuss solubilities in more detail later, where you will learn that very small amounts of the constituent ions remain in solution even after precipitation of an insoluble salt. The number of grams in 2.65 mol of SO2 is. I. Soluble chromates react with barium ion to form a finely divided yellow precipitate of barium chromate: \[\ce{Ba^{2+}(aq) + CrO4^{2-}(aq) <=> BaCrO4(s)}\] Barium chromate is soluble in mineral acids, but only slightly soluble in acetic acid. Legal. B) enthalpy and entropy are of equal importance in determining the spontaneity of a reaction. What is the balanced equation for ammonium carbonate is heated, it decomposes into ammonia gas, carbon dioxide gas, and water vapor? energies: . This unbalanced equation has the general form of an exchange reaction: \[ \overbrace{\ce{AC}}^{\text{soluble}} + \overbrace{\ce{BD}}^{\text{soluble}} \rightarrow \underbrace{\ce{AD}}_{\text{insoluble}} + \overbrace{\ce{BC}}^{\text{soluble}} \label{4.2.2} \]. Net ionic equation: The chemical equation which is balanced and shows only chemical species that participate in the reaction. dissociation energies: Potassium iodide + Lead II Nitrate 7. Write the balanced molecular equation, complete ionic equation, and net ionic equation for the reaction that occurs between aqueous solutions of cobalt(II) sulfate and barium chloride. Which statement regarding balanced chemical equations is not true? S + O2 SO2 + 70.8 kcal. 2) If we wrote the balanced complete ionic equation, we would see this: Activation energy can best be described as the. the balanced equation for ammonium hydroxide and perchloric acid is given below.NH4OH (aq) + HCl (aq) ---> NH4Cl (aq)+ H2O (l) .Above is the balanced molecular Equation. Balance the equation H8N2O4S + Ba(C2H3O2)2 = BaO4S + NH4C2H3O2 using the algebraic method or linear algebra with steps. Solution: . Consider the balanced equation shown and identify the statement that is not true. Aqueous solutions of strontium bromide and aluminum nitrate are mixed. 2 AgNO3(aq) + K2SO4(aq) 2 KNO3(aq) + Ag2SO4(s) Calcium hydroxide ("slaked lime") and sulfuric acid react to produce calcium sulfate and water according to the following balanced equation: Ca (OH) 2 (aq) + H 2 SO 4 (aq) CaSO 4 (s) + 2 H 2 O (l) a. ammonia + sulfuric acid ==> ammonium sulfate. Aluminum + Iodine I O. 2.ammonium carbonate and calcium chloride. NH,SO4 (aq) + BaC2H302 (aq) -- BaSO4(s) + NH4C2H2O2 (aq). To determine whether a precipitation reaction will occur, we identify each species in the solution and then refer to Table \(\PageIndex{1}\) to see which, if any, combination(s) of cation and anion are likely to produce an insoluble salt. In the reaction energy diagrams shown, reaction B is ________, and it occurs ________ reaction B. . B) The molar mass of any compound is equal to its molecular weight in grams. These ions are called spectator ions because they do not participate in the actual reaction. Assign variables to each unknown coefficient. 3) In order to produce 5.65 moles Step 10: Reaction (i) Potassium chloride + ammonium phosphate. For example, C6H5C2H5 + O2 = C6H5OH + CO2 + H2O will not be balanced, but XC2H5 + O2 = XOH + CO2 + H2O will. 8/31/2015. Because ionic substances such as \(\ce{AgNO3}\) and \(\ce{K2Cr2O7}\) are strong electrolytes (i.e., they dissociate completely in aqueous solution to form ions). there are equal numbers of atoms on each side of the reaction arrow. This change in state is To fix this unbalanced equation a 5 in front of the O2 on the left hand side is added to make 10 O's on both sides resulting in. What is the actual yield of the Read our article on how to balance chemical equations or ask for help in our chat. Science Chemistry Write the balanced equation to this reaction: 3.142 g of ammonium phosphate reacts with 1.648 g of barium l hydroxide in water to give ammonium hydroxide and barium phosphate Write the balanced equation to this reaction: 3.142 g of ammonium phosphate reacts with 1.648 g of barium l hydroxide in water to give ammonium hydroxide . D) occur at high temperatures, but not at lower temperatures. For the total ionic equations, write strong electrolytes in solution in the form of aqueous ions. (NH4)2SO3 (aq) + Ba(C2H302)2 (aq) - BaSO3(aq) + NH.C2H3O2 (aq). (II) sulfate, you look it up and find it to be soluble. dioxide, CO2. The left hand side has 2 O's and the right hand side has 10 O's. (NH4)2SO4 (aq) + Ba(C2H302)2 (aq) - BaSO4(s) + 2 NH C2H2O2 (aq). Write the overall chemical equation, the complete ionic equation, and the net ionic equation for the reaction of aqueous silver fluoride with aqueous sodium phosphate to give solid silver phosphate and a solution of sodium fluoride. Chemical reaction. to form the chloride ion. The anion would only be chloride if the other four tests proved to be negative. 3/12 . B) from what is being oxidized to the substance being reduced. The net ionic equation is as follows: \(Pb^{2+} (aq) + 2I^-(aq) \rightarrow PbI_2(s) \), \(Fe^{2+}(aq) + 2OH^-(aq) \rightarrow Fe(OH)_2(s)\), \(2PO_4^{3-}(aq) + 3Hg^{2+}(aq) \rightarrow Hg_3(PO_4)_2(s)\), \(Ca^{2+}(aq) + CO_3^{2-}(aq) \rightarrow CaCO_3(s)\), Predicting the Solubility of Ionic Compounds: Predicting the Solubility of Ionic Compounds, YouTube(opens in new window) [youtu.be] (opens in new window). Asked for: reaction and net ionic equation A Because barium chloride and lithium sulfate are strong electrolytes, each dissociates completely in water to give a solution that contains the constituent anions and cations. Use uppercase for the first character in the element and lowercase for the second character. Based on the reaction shown, which statement is true? If 0.68 mole of NO is reacted with 0.79 mole of O2 to produce NO2, the limiting reactant is, Which is the limiting reactant when 3.00 g of calcium are reacted with 8.00 g of water to produce hydrogen burned in a grilling session, how many moles of carbon dioxide gas are formed? Balanced symbol equation . The balanced equation for the reaction between aqueous ammonium sulfate and aqueous barium acetate is (NH4)2SO4 (aq) + Ba(C2H302)2 (aq) - Baso, (aq) + 2 NH.C2H2O2 (s). . dioxide, CO2. Balanced Equation: Net Ionic Equation: 3. ammonium sulfide and lead (II) nitrate. To balance a chemical equation, enter an equation of a chemical reaction and press the Balance button. (NH4)2SO4 (aq) + Ba(C2H202)2 (aq) - BaSO4(s) + NHC2H2O2 (aq). You can use parenthesis () or brackets []. In the reaction 2 C + O2 2 CO, how many moles of carbon are needed to produce 66.0 g of carbon In order for this equation to be balanced, there must be an equal amount of Na on the left hand side as on the right hand side. Most of these kinds of equations are double displacement reactions: AX + BY 6 AY + BX 2. l. Potassium + Iodine 2. II. herculoids gloop and gleep sounds In a reaction to produce chlorine gas, the theoretical yield is 25.6g. Use uppercase for the first character in the element and lowercase for the second character. How many moles of This reaction is ________ because the sign of H is ________. (NH4)2SO4 + Ba (NO3)2 ==> 2NH4NO3 + BaSO4. C3H8 (2 C-C, 8 C-H bonds); O2 (1 O=O); (2 C=O bonds); (2 O-H bonds). A) precipitation 8/31/2015. B) The number of atoms in one mole of platinum is the same as the number of atoms in one mole Consider the reaction shown: 280.mL. Which of the following can affect the activation energy of a reaction? ________ C8H18 + ________ O2 ________ CO2 + ________ H2O, All of the reactions shown are oxidation-reduction reactions except. The combination of ions most likely to produce a precipitate is. Acid rain forms in the upper atmosphere by the reaction of sulfur trioxide with water forming Given: reactants. Calcium nitride + water 3. B) enthalpy and entropy are of equal importance in determining the spontaneity of a reaction. Just as important as predicting the product of a reaction is knowing when a chemical reaction will not occur. The balanced equation will appear above. Calculate the pH\mathrm{pH}pH of the solution at 25C25^{\circ} \mathrm{C}25C. (i) Balanced equation: Ba2+ + 2 F BaF 2 Two points are earned for the correct reactants (1 point each). One point is earned for correctly balancing the equation for atoms and charge. In the following reaction which species is being oxidized and which is being reduced? Copy Table into your notebook and use Ohm's equation to fill in the blanks. Identify the ions present in solution and write the products of each possible exchange reaction. As you will see in the following sections, none of these species reacts with any of the others. Two important uses of precipitation reactions are to isolate metals that have been extracted from their ores and to recover precious metals for recycling. CH4 + 2 O2 CO2 + 2H2O Increasing the concentration of reactants he reaction N2 + 3 H2 2 NH3 is used to produce ammonia. Classify the following ionic compounds as soluble or insoluble: (a) silver sulfate (Ag 2 SO 4 ), (b) calcium carbonate (CaCO 3 ), (c) sodium phosphate (Na 3 PO 4 ). Mothballs vaporize in a closet. Hence, there will be not net ionic equation. V. Cake mix is manufactured from five basic ingredients. How many moles of CO2 are produced when 2.5 moles of O2 react according to the following Use the calculator below to balance chemical equations and determine the type of reaction (instructions). One mole of Mascagnite [(NH4) . Since there are 7 oxygen atoms on the right and only 3 on the left, a 3 is placed before O2, to produce the balanced equation: In reactions involving many compounds, equations can be balanced using an algebraic method, based on solving a set of linear equations. Calculate the % yield of the reaction. Precipitation reactions are a subclass of exchange reactions that occur between ionic compounds when one of the products is insoluble. There must be the same quantities of each atom on each side of the equation. All of the statements regarding redox reactions are true except 35) Magnesium Hydroxide . D) One mole of sodium chloride, NaCl, contains the same number of ions as one mole of calcium When potassium hydroxide and hydrobromic acid are combined the products are, The scientific principle which is the basis for balancing chemical equations is. CH4 (4 C-H bonds); O2 (1 O=O); (2 C=O bonds); (2 O-H bonds). Copper(II) sulfate + barium chloride Observations blucian white Molecular equation 2cuso Bach CuCl(s) +BaSO4 (ag). 1; 2; 3; 4; To fix this 2 more Na's are added on the left side. 70.8 kcal are produced when 32.1 g of sulfur reacts. Since there are an equal number of atoms of each element on both sides, the equation is balanced. The balanced equation will appear above. Compound states [like (s) (aq) or (g)] are not required. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Consider the reaction shown: Label Each Compound With a Variable. 8/31/2015. 2 Cr(s) + 3 Cl2(g) 2 CrCl3(s), The oxidation number of iron in the compound FeBr3 is, The combination of ions least likely to produce a precipitate is, When the reaction shown is balanced, there are ________ atoms of oxygen and ________ atoms of hydrogen on each side._______ (NH4)2SO4(aq) + _______ Ba(C2H3O2)2(aq) _______ BaSO4(s) + _______ NH4C2H3O2(aq), The scientific principle which is the basis for balancing chemical equations is, When a solution of iron(III) nitrate is mixed with a solution of sodium hydroxide, a rust colored precipitate forms. When 1 mol P4(s) reacts, 435.2 kcal are released. In doing so, it is important to recognize that soluble and insoluble are relative terms that span a wide range of actual solubilities. Using the equation below, determine how many kilograms of ammonia will be N2 = 226 kcal/mol Barium Peroxide BaSO4 Barium Sulfate BBr3 Boron Tribromide BCl3 Boron Trichloride BeCl2 Beryllium Chloride BeI2 . Use uppercase for the first character in the element and lowercase for the second character. hen 1 mol P4(s) is produced, 304.0 kcal are consumed. They can therefore be canceled to give the net ionic equation (Equation \(\ref{4.2.6}\)), which is identical to Equation \(\ref{4.2.3}\): \[\ce{2Ag^{+}(aq) + Cr_2O_7^{2-}(aq) \rightarrow Ag_2Cr_2O_7(s)} \label{4.2.6} \]. For a chemical reaction to occur, all of the following must happen except. There is now one Barium, one Sulfate, two hydroxides, and two oxygens on either side of the arrow. Simple chemical equations can be balanced by inspection, that is, by trial and error. could. E) refers to the free energy of the reaction. Replace immutable groups in compounds to avoid ambiguity. . famous shia personalities in pakistan pat bonham net worth. The current study focused on the efficiency of applying small amounts of NFs incorporated with conventional . All salts of Group IA, and ammonium are soluble. Ammonium sulfate is a common component of fertilizer. The unbalanced chemical equation that describes this neutralization reaction looks like this #"CH"_ 3"COOH"_ ((aq)) + "NaOH"_ ((aq)) -> "CH"_ 3"COONa"_ ((aq)) + "H"_ 2"O"_ ((l))# Now, you could check to see if this chemical equation is balanced by counting the number . To simplify comparisons, the energy value of fuels is expressed in units of. sodium carbonate and iron ii chloride ionic equation. Direct link to this balanced equation: Instructions on balancing chemical equations: Enter an equation of a chemical reaction and click 'Balance'. By changing the scalar number for each molecular formula, the equation may be balanced. Ammonium sulfate react with barium chloride to produce barium sulfate and ammonium chloride. C) The molar mass of a diatomic element is its atomic weight in grams times two. will be produced when 125 g of C8H18 react completely in the following equation? A) the value of G is less than zero. C) A mole of any compound contains one mole of each kind of atom found in that compound. Which factors would decrease the rate of a reaction? D) when a substance is oxidized its charge (or oxidation number) decreases. Increasing the temperature Write balanced formula equations for these reactions and identi6r the type of reaction. Use the calculator below to balance chemical equations and determine the type of reaction (instructions). An outline of the digestive organs appears on x-rays of patients who have been given a barium milkshake or a barium enemaa suspension of very fine BaSO4 particles in water. To obtain the complete ionic equation, we write each soluble reactant and product in dissociated form: \[ \ce{3Ba^{2+}(aq)} + \cancel{\ce{6NO_3^{-}(aq)}} + \cancel{\ce{6Na^{+} (aq)}} + \ce{2PO_4^{3-} (aq)} \rightarrow \ce{Ba_3(PO_4)_2(s)} + \cancel{\ce{6Na^+(aq)}} + \cancel{\ce{6NO_3^{-}(aq)}} \nonumber \]. 5H2O. Which statement concerning the mole concept is not true? See answer (1) Copy. A solid sample at room temperature spontaneously sublimes forming a gas.

Family Depression Quotes, Shoprite Loyalty Card Number Lookup, Clayton County Eviction Help, 350 Legend Ar Accessories, Richard Lamb Obituary, Articles B